Yeah, that curve looks incredibly wrong to me--way boosted in the treble. As Adam would say, "There's your problem!"
Also, 5 channel stereo kinda stinks--try using DTS:Neo 6 or Dolby Pro Logic IIx+eXTremeSTiUltra.
That will definitely give you a different sound. I'd also experiment with regular stereo, so you know what you're messing with when you turn on the surround modes.